Is it possible to have two different values for a reaction parameters? One for the top meters of the soil profile and one for the rest.
I want to do this in order to only allow for mineralization of org-N to ammonium at the top part of the profile.
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Sure. You need to define two different materials and then for each you can have some properties different (e.g., reactions) and others the same (e.g., soil hydraulic - to have uniform soil profile). J.